Tag Archives: material chemistry

Cool Clothing, Literally!

With no solution on how to reduce greenhouse gas emissions, the concept of personal thermal management is becoming a promising alternative to renewable energy resources. Personal thermal management focuses on cooling or heating the human body instead of an entire building. This is the most cost-effective way to solve the energy dilemma.

A team of researchers at Stanford University have found one way of reducing energy consumption by demonstrating the use of nanoporous polyethylene (nanoPE) as a textile for human clothing. They predict that this fabric could reduce the amount of energy used for air conditioning.

A portion of heat from our bodies is released through the emission of IR radiation in the range of  7 – 14 nm. Many of the fabrics we wear have chemical groups that absorb radiation in that range. One fabric, Polyethylene, is transparent to IR but it is also transparent to visible light which is not desirable as it causes our bodies to increase in temperature.

Figure 1. The schematics of human body radiation, visible light and air convection. Source: Cui et al., 2016

However, Ci Yui and his colleagues at Stanford University hypothesized that if polyethylene had pores between 50 – 1000 nm in diameter then it could scatter visible light, making it opaque, but still allow IR to pass through. Fortunately, such a material already exists and is commercially available. Lithium-ion batteries use nanoPE as a separator between anodes and cathodes to prevent electrical shortages.

Figure 2. The total IR transmittance of bare skin, normal PE, nanoPE, cotton, Tyvek and PDA-nanoPE-mesh. Credit; Cui et al., 2016

Yui and his team used a device to simulate the heat output of skin and tested the cooling effects of nanoPE, cotton and Tyvek, a fibrous polyethylene textile manufactured by DuPont. They found that compared to cotton, nanoPE was able to cool bare skin by 2.7°C more. In addition, nanoPE was the only material of the three tested to reveal the H-shape, mimicking bare skin,  because of its IR transparency.

Figure 3. Thermal measurement nanoPE, cotton and Tyvek. (A) The device used to simulate the heat out put of skin. A thermocouple is used to measure temperature. (B) The thermal measurement of each material. (C) Thermal imaging of bare skin and the three materials tested. Source: Cui et al., 2016..

“That may not sound like much, but in terms of energy savings it actually could be huge”, says Svetlana Boriskina of Massachusetss Institute of Technology, who wrote on the Yui’s findings in Science. She points out that setting a home’s thermostat a few degrees lower can cut energy use up to 45%.

To make the material more appealing, Yui and his team coated the nanoPE to wick away moisture to keep the wearer feeling dry.” Yui and his colleagues may have demonstrated another function of nanoPE, but more research is needed to test for its comfort, durability and a way to colour the material with dyes that won’t block IR radiation.” adds Boriskina.

-Ashlea Ahmed

Resources:

Hsu, P.; Song, A.; Catrysse, P.; Liu, C.; Peng, Y.; Xie, J.; Fan, S.; Cui, Y. Radiative Human Body Cooling by Nanoporous Polyethylene Textile. Science [Online] 2016, 353, 1019-1023 http://science.sciencemag.org/content/sci/353/6303/1019.full.pdf (accessed Mar 4, 2018).

Scientific American. Newest Material Makes Coolest Clothing Around.https://www.scientificamerican.com/article/new-material-makes-coolest-clothing-around/ (accessed Mar 4, 2018).

 

 

 

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Can Cigarette Butts Be the Next Huge Source of Fuel?

Over a billion people all over the world smoke on average six trillion cigarettes every year and their littered cigarette butts pose a large environmental waste and water pollutant problem to the community and wildlife. However, a study done by researchers at the University of Nottingham uncovered that these waste products can be used as a source of hydrogen storage material.

Figure 1: Cigarette Butts                                          Source: Flickr by Alexander C. Kafka

As of November 2017, Materials Chemistry Professor Dr. Mokaya and his undergraduate student Troy Blankenship successfully converted cigarette butts into the starting materials needed for hydrogen storing. Hydrogen can be used as an energy source because of its capacity to generate heat when burned or electricity when reacted with oxygen. This new discovery pushes industries closer in the direction to switch from coal based material to biomass or waste based reusable material for power and fuel.

Cigarette butts contain cigarette filters, a non-biodegradable film base material, called cellulose acetate. These compounds have been a popular subject of waste valorization, a form of converting existing biomass into high performance produce. Cigarette butts produce porous carbons, which have the highest hydrogen storage capability to be currently documented. These findings have a major impact on reducing the litter on public properties and the environmental pollutant of cigarette butts. Toxic heavy metals are found in cigarettes and can wash up into large bodies of water, possibly harming humans and wildlife.

Figure 2: Cellulose Acetate                       Source: Google by Wikimedia Commons

The littered cigarette butts undergo a process of hydrothermal carbonization by adding only water and heat to synthesize a carbon compound called hydrochar. Hydrothermal carbonization imitates the natural process of coal formation in a close container subject to high temperature and intense pressure. Once this product is activated, the compound becomes highly oxygenated, rich in pore volume and increased in surface area. To measure the hydrogen concentration, the compound was weighed before and after the addition of purified hydrogen. Hydrochar can then store hydrogen that can replace gasoline to fuel vehicles and other forms of transportation or natural gas to heat buildings and houses.

Linked Vimeo Video: Biomass Animation by David Curtis

Further research needs to be done in the production of sustainable energy storage materials in the investigation of valorization possibly solving the waste of 800,000 metric tons of cigarette butts produced every year. With oil increasing in value, decreasing in amount and massive increase in carbon dioxide emissions, the need to stray away from fossil fuels is bigger than ever.

-Tiffany Liew

References:

Marksman, D.E., Pirverdyan, A.I., Mokhnachev, I.G., & Perepechkin, L.P. Cellulose acetate fibre for cigarette filters. Fibre Chem. 1971, 3, 292-293.

Mokara, R., & Blankenship, T. Cigarette butt-derived carbons have ultra-high surface area and unprecedented hydrogen storage capacity. Energy Environ. Sci.  2017, 10, 2552-2562.

Tuck, C.O, Perez, E. Horvath, I.T., Sheldon, R.A., & Poliakoff, M. Valorization of Biomass: Deriving More Value from Waste. Science. 2012, 337, 695-699.

Weavable Light-Emitting Fibers for Wearable Electronics

Integration of electronics into textiles (e-textiles) has emerged as a promising new technology because it can offer tremendous possibilities in many fields of science and fashion, leading to new applications and products.

Organic light-mitting fibers woven into knitted clothes. Source: The Korea Advanced Institute of Science and Technology (KAIST)

Numerous studies have been dedicated to developing the organic light-emitting fibers for wearable electronics. However, conventional fibre-based light emitting devices have limitations of their much lower emission performance compared to those fabricated on flat substances. So, a research team led by Professor Kyung Cheol Choi in the School of Electrical Engineering at Korea Advanced Institute of Science and Technology (KAIST) in South Korea has developed a simple and cost effective solution which is a fabrication technique, using a low-temperature process. Using their technique, the team successfully fabricated the thin and flexible fibre-based organic light-emitting diodes (fiber OLEDs) without any reduction in performance.

A video below briefly introduces OLED fibers. See source here.

https://www.youtube.com/watch?v=J9keKez6ryY

In the manufacturing process, eliminating the high temperature and vacuum processes is crucial since fibers such as cotton, polyester, nylon are thermally delicate. So, the research team used a thermal annealing and dip coating method in cylindrical fibers at as low temperature as possible. 

The team also designed the structure of fiber OLEDs to improve the electron injection efficiency on the fibers and to employ a low-temperature thermal annealing processable cathode, which significantly impacts on its performance. According to the researchers, their revised structure clearly exhibited high luminance and current efficiency compared to those of previously reported fiber-based OLEDs. In addition, the dip coating method at low temperature improved surface roughness and sufficiently ensured the device stability without any planarization layer.

Moreover, the technology demonstrates the scalability of the proposed fabrication scheme with diameter ranging from 300μm to 90μm, thinner than human hair. The research team ensured that the fiber OLEDs could be weavable into textiles and knitted clothes without any reduction in emission performance because their inherent empty spaces and the wavy structures enhance flexibility and stress distribution of the OLEDs.

Fiber OLEDs with different diameters. Source: The Korea Advanced Institute of Science and Technology (KAIST)

Professor Choi emphasized the versatility for application on delicate fibers by stating that the technology to incorporate display screens into our clothing is now a reality, and organic light-emitting clothes will have a significant influence not only on the e-textile industry, but also on the automobile and healthcare industries.

A video below briefly shows how wearable e-textiles may be used in future.      See source here.

Reference:

  1. Seonil Kwon, Hyuncheol Kim, Seungyeop Choi, Eun Gyo Jeong, Dohong Kim, Somin Lee, Ho Seung Lee, Young Cheol Seo, Kyung Cheol Choi. Weavable and Highly Efficient Organic Light-Emitting Fibers for Wearable Electronics: A Scalable, Low-Temperature ProcessNano Letters, 2017; 18 (1): 347 DOI: 10.1021/acs.nanolett.7b04204
  2. The Korea Advanced Institute of Science and Technology (KAIST). (2018, January 10). Fiber OLEDs, thinner than a hair. ScienceDaily. Retrieved January 15, 2018 from www.sciencedaily.com/releases/2018/01/180110101019.htm
  3. The Korea Advanced Institute of Science and Technology (KAIST). (2017, September 4). Light-emitting fibers for wearable displays. AsianScientistNewsroom. Retrieved January 15, 2018 from https://www.asianscientist.com/2017/09/tech/oled-flexible-wearable-display/

-Subi Kim