Tag Archives: pollution

The Future of Fighting Plastic Pollution : Enzymatic Plastic Breakdown

Plastic Pollution

With plastics being one of the most used materials for making many goods, it is no wonder that Canadians produce an estimated 3.3 million tonnes of plastic waste per year .Plastic pollution is an issue that has been present in the environmental community for some time now, as the effects of plastic pollution are far-reaching, even affecting tap water around the world, and harming marine wildlife through entanglement around the animal’s body. Some species like sea turtles eat the plastics, and this ends up blocking their digestive tract, resulting in starvation. This issue is not just restricted to turtles, and other animals such as whales also deal with this, as many whales have had large amounts of plastics found in them.  The video below by Kurzgesagt goes into the topic of plastic pollution more in-depth if you are interested in learning further about it.

 

Plastic Eating Bacteria & PET

Scientists had tried to combat this issue with a plastic-eating bacteria, that was initially found at a plastic recycling plant in Japan in 2016, but later on, when experimenting with the bacteria, the enzyme PETase was discovered. This enzyme works around twenty percent faster than the actual bacteria did at degrading PET, a very popular plastic used in many common items such as plastic bottles, and clothing. At the time, however, even PETase was not yet fast enough to be considered for widespread or commercial use.

Plastic Bottle Pollution in Armenia

Plastic Bottle Pollution in Armenia. Image: By UNDP in Europe and Central Asia

 

A Super Enzyme is Made

Recently, the same scientists who studied the PETase enzyme have made another improvement. In a new study, they show that by simply mixing PETase and MHETase (another enzyme) with one another, great improvements are made in the speed of PET degradation. After actually developing an enzyme from the PETase and MHETase to make a much stronger one, they developed an enzyme with PET breakdown that was three times faster than what they had previously achieved.

A diagram breakdown from the original PETase paper, with PET items being broken down by PETase and then further by MHETase. Source : https://www.pnas.org/content/115/19/E4350

Looking Forward

While the enzyme might still not be strong enough to combat global plastic pollution on a large enough scale, it does show how progress is slowly being made towards a safer and cleaner future. After finding the plastic-eating bacteria, improvements were implemented to create a faster enzyme, and then once again, making it even faster. The incremental gains in knowledge like these are what helps develop new technologies that help propel us further as species by combating issues in unique and innovative ways.

 

– Mehdi Mesbahnejad

COVID-19: Environmental Impacts of the Masks

Have you ever thought that the masks we are wearing everyday might be polluting the environment? With the rise of COVID-19 pandemic, usage of masks have become such a natural and crucial part of people’s lives. However, as production and disposal of masks increase, environmental consequences of used masks are starting to be observed.

Corona, Mask, Waste, Coronavirus, Covid-19, Pandemic

Corona Mask Waste“, by Roksans96, licensed under Pixabay

Why are the masks being environmental threat?

Among many different types of masks currently produced, the most commonly used one are the surgical masks. High usage of surgical masks is due to safety provided by anti-droplet polypropylene filter layer of the masks. Since COVID-19 is known to be a droplet-borne disease, polypropylene filter layer became favorable feature to many individuals, especially to those working in hospitals and medical field. Given the fact the medical field workers are needed more than ever before with increasing number of infected individuals, production and disposal of surgical masks and polypropylene filter layer became inevitable.

File:Face masks during the COVID-19 pandemic.jpg

“Face masks during the COVID-19 pandemic“, by Paladin Zhang, licensed under CC BY 2.0

The concern lies in that surgical masks are mostly disposed after a single use because of possible bacterial cross-contamination upon multiple usage. Polypropylene is not readily biodegradable, which means as its usage escalates rapidly, its disposal might end up being long-lasting environmental concern.

Impact on marine ecology

Some of the environmental issues regarding mask wastes are already observable in some parts of the world. One of the first countries to face the environmental consequences of mask litter was Hong Kong, which was one of the first countries to face COVID-19 outbreak.

YouTube Preview Image

Description: Soko Island in Hong Kong polluted with COVID-19 mask waste.

Video Credit: South China Morning Post

Many of masks litters ended up in the coastal areas, where the wastes appeared to be serious threat to the marine ecology. Many marine predators might swallow mask wastes confusing the masks with their preys, and birds that live near coastal area are often entangled by disposed mask wastes.

pollution drina plastic waste free photo

“Pollution Drina Plastic Waste Free Photo“, by geraldsimon00, licensed under Pixabay

How is this issue being addressed?

After direct environmental impacts of mask wastes were observed, the need for more eco-friendly masks was highlighted. Therefore, scientists started working on development of mask materials that can replace polypropylene while keeping the strong anti-droplet effect of the filter layer.

One of the approaches were made by BioProducts Institute at the University of British Columbia. The research team attempted using wood fibers from local trees to make filter layer. Wood fibers are easily biodegradable, so even if mask litters end up in the environment, it would not be an environmental threat.

Another approach was made by Hong Kong Polytechnic University. The research team in the university used laser to induce properties of graphene on the mask. Graphene is hydrophobic, which means that it is effective in repelling droplets. Also, graphene has photothermal property, meaning it heats up under extensive exposure to sunlight. In this process, mask can be sterilized, and this antibacterial activity allows multiple reuse of masks. In this way, the amount of mask disposed will decrease significantly.

The ideal crystalline structure of graphene is a hexagonal grid.”, by AlexanderAlUS, licesned licensed under CC BY 2.0

However, all of the scientific technologies are still in developing stages. There are still some concerns in applying them to commercial masks yet. Still, with many scientist putting efforts to overcome this issue, I believe the solution will be found soon.

– Tae Hyung Kim

Excess carbon dioxide: How can we combat this problem, and why is it problematic for marine organisms?

Did you know that excess carbon dioxide poses a significant problem for marine life? Although CO2 is naturally occurring and acts as an important heat-trapping gas in moderate amounts, human activities have pumped lots of excess CO2 into the atmosphere.

Exhaust fumes from an industrial plant, which includes carbon dioxide (as well as other chemicals). Photo by Damian Bakarcic.

Too much carbon dioxide not only contributes to more extreme weather and global warming, but it also made oceans 30% more acidic since the beginning of the Industrial Revolution.

Today, CO2 makes up 84% of all greenhouse gases from human activity, with around 40 billion tons being produced per year.

Numerous climate scientists, such as climatologist Dr. James Hansen, state that to avoid the impacts of climate change, the levels need to be reduced to at maximum 350 ppm. However, CO2 levels have already exceeded 400 ppm in 2019.

Across the world, many different marine species, such as barnacles, experience the chemical effects of lowered pH levels. This comes in the form of problems with shell formation/ adhesion and lower survival rates, as demonstrated in a laboratory study by the Northeast Coastal Acidification Network.

Ocean acidification has an especially adverse impact for animals that are sensitive to changes in carbonate chemistry. For example, shellfish use carbonate in the ocean to make their protective shell structures. With a low pH, calcium carbonate is in short supply because it will react with acidic solutions.

An infographic depicting the chemistry behind ocean acidification, and why it is harmful for marine life. Source: Climate Commission (RIP)

One remedy involves catalysis. This uses catalysts to convert CO2 into useful goods – fertilizers and plastics. Doing so would convert the polluting waste product into useful molecules, and simultaneously lessen our need to use fossil fuels to generate such products.

A way this can be achieved is with an electrolysis cell, which employs electrical energy to run a non-spontaneous redox (i.e. oxidation-reduction) reaction. A non-spontaneous redox reaction occurs only when an external voltage is applied, whereas a spontaneous one would generate a voltage itself.

On the electrode surface, the CO2 is reduced – meaning the addition of hydrogen, the removal of oxygen, or both (oxidation is the opposite: lose hydrogen/ gain oxygen). Depending on the number of electrons transferred, many different molecules could be produced. The products form in the electrolyte, and move to a separation system.

Catalysis involving carbon dioxide and hydrogen, with a Cu/ZnO catalyst. CO2 is reduced, producing methanol and carbon monoxide. Source: a drawing by myself.

Any unreacted CO2 and the electrolyte are recycled. Tin is a metallic catalyst used to make formic acid via catalysis. More complex molecules can be formed as well, such as the ethanol found in hand sanitizers.

In conclusion, too much carbon dioxide is a significant threat to marine life, and catalysis is one solution that scientists are investigating to recycle CO2. Are there other potential solutions for excess CO2 that you know of?

– Jacqueline (Wai Ting) Chan