Author Archives: jessicashii

Lead-based Invisible Ink: Revolutionizing Data Encryption

James Bond, get ready to put your skills to the test.

The images depict printed patterns created by the lead-based invisible ink, shown under UV light. From left to right: Butterfly with intricate details, QR codes, text in English. Photo Credits: Congyang Zhang et al., 2017.

Scientists from People’s Republic of China created an invisible ink that easily switches on and off. These findings, published in the journal Nature as a research article titled Conversion of invisible metal-organic frameworks to luminescent perovskite nanocrystals for confidential information encryption and decryption, provide a glimpse into the future of high-security information encryption. Unfortunately, there’s one huge drawback: lead, the invisible ink’s main component, can be poisonous in large quantities.

Invisible ink uncovers counterfeit money and stores private information by keeping written content hidden from the naked eye. Ideally, invisible ink remains undetected until treated with UV light, however, previous invisible inks left residues resembling wet paper. The new lead-based invisible ink material leaves no residue, hiding secret information unsuspiciously.

Lead-based invisible ink is composed of a yellow powdered salt which turns clear in solution. The salt, composed of extremely tiny crystals known as nanocrystals, glow under UV light.

The powdered salt, shown in normal light (left) and UV light (right) This salt MABr is the foundation for the on/off switching properties of lead-based invisible ink. Photo Credits: Congyang Zhang et al., 2017.

The lead-based ink becomes invisible with the addition of methanol, a common antifreeze. UV light cannot detect the ink after the methanol treatment, making the invisible ink undetectable. The hidden lead-based ink, easily passed around without fear of UV detection, will safely enclose the confidential information. Reapplication of the custom-made salt triggers the ink’s UV-detectable properties, making the information visible again. This manual on/off switch adds an extra layer of protection against UV lights.

Reversibly switching of invisible ink: The researchers’ university logo is encrypted by methanol (MeOH) and then decrypted by adding salt (MABr). All three images are shown under UV light. Photo Credits: Congyang Zhang et al., 2017

The scientists found the ink did not fade over a testing period of three months; the ink lasted over 20 on/off switches. This means the lead-based ink can be useful for long-term important documents. Realistically, the toxic lead component must be replaced by safer alternatives before the ink can be used globally.

Although scientists plan to use the lead-based invisible ink mainly for increasing security of anti-counterfeit measures, the ink’s virtually undetectable qualities must be approached with skepticism. In the wrong hands, such as the hands of corrupt spies and drug lords, this lead-based invisible ink can destroy our society.

Will the potentially life-changing applications of this on-and-off invisible ink outweigh the risky consequences?

Only time will tell.

– Jessica Shi

Toxicity in Chocolate

If you own or plan to own a dog, you may have heard the horror stories about dogs accidentally eating chocolate. How can something so delicious be so harmful to dogs?

One can only imagine that dogs crave chocolate as much as we do. Photo Credits: Dr. Mark

The toxic component of chocolate is cocoa powder, processed from cocoa beans. Cocoa powder contains theobromine, a compound which stimulates the nervous system and increases feelings of arousal. Whereas theobromine has no adverse side effects to humans, it can cause discomfort to dogs; over-consumption of chocolate can lead to vomiting, diarrhea, seizures, and sudden death.

Breaking down the components of chocolate.
Photo Credits: Andy Brunning

Chocolate is known for its euphoric and addictive qualities, even becoming comparable to that of a drug. Although most people recognize chocolate as a harmless sweet, ‘the dose makes the poison‘ is crucial to evaluate when chocolate consumption becomes toxic. Canine digestive systems can only process theobromine in small amounts.

There are two main factors influencing the toxicity of chocolate to dogs: chocolate type and dog size.

Baking chocolate and chocolate chips contain the highest milligrams of theobromine per kilogram of chocolate than other chocolate types. The whiter the chocolate, the less theobromine is present, so white chocolate causes the least amount of internal damage per ounce.

Average theobromine levels in different types of chocolates. Photo Credits: PetPlan

In terms of dog sizes, larger dogs can consume more chocolate compared to small dogs because they weigh more. For example, a 75 lb golden retriever will reach the theobromine limit at after 15 ounces of milk chocolate (roughly 10 Hershey bars), whereas a 5lb pomeranian will reach the theobromine limit at 2.5 ounces of milk chocolate (roughly 1.5 Hershey bars).

There is an algorithm to determine the amount of theobromine a dog can safely consume. Photo Credits: PetPlan

Unfortunately white chocolate is not completely safe for dogs. Although it contains the lowest level of theobromine, white chocolate contains high fat and sugar levels since it uses cocoa butter instead of cocoa powder. Dogs do not process sugar or fat easily, and overconsumption of white chocolate could result in enteritis or pancreatitis!

As long as this dog does not consume the entire box, he or she will be alright. Photo Credits: dogsaholic.com

The most important fact is that chocolate consumption, like all food in life, is dose-dependent. There is no need to panic if your dog breaks into the snack cupboard and gobbles down a small chocolate bar.

Jessica Shi

Extragalactic Attack: Key to the Universe?

Radiation from cosmic rays could severely damage the brains of astronauts.

Radiation from cosmic rays could cause severe brain damage, according to a study on Mars astronauts. Photo Credits: Diana Quach

Cosmic radiation has been linked to Alzheimer’s disease, premature aging, and dementia in astronauts because it damages neurons in the brain. This is extremely concerning for anyone who wants to understand life beyond earth; sending astronauts for long space missions could destroy their lives! For decades, scientists have attempted to combat the impact of intergalactic cosmic radiation on Mars. On September 22nd, a new discovery changed everything.

Scientists recently discovered extragalactic high-energy cosmic rays, which are radiative fragments of atoms that cascade into earth at the speed of light. Scientists previously hypothesized that cosmic rays exist outside our galaxy, but were unable to prove it until now. The Pierre Auger Observatory’s particle detectors revealed that these rare cosmic rays are a million times more powerful than the largest cosmic phenomena in our galaxy. These findings were published in the journal Science as a research article titled Observation of a large-scale anisotropy in the arrival directions of cosmic rays above 8x10e18 eV.

Evidence shows that cosmic rays with large energies originate beyond our galaxy, shown through a flux diagram.

This map of the sky shows the cosmic ray flux, with a cross marking the specific region where scientists observed a pattern of cosmic rays. Photo Credits: The Pierre Auger Collaboration.

The Pierre Auger Collaboration is certain that these high-energy cosmic rays originate outside our galaxy. Although cosmic rays are emitted by the Milky Way, the intergalactic particles cannot contain as much energy as the rays detected.

The blue lines represent magnetic field lines in a black hole that project an extragalactic jet, similar to our galaxy’s magnetic field. Photo Credits: NASA/JPL-Caltech

Extragalactic cosmic rays could contribute to the radiation damage to astronauts since they are so high in energy. Previously, scientists have considered many intergalactic cosmic radiation because there was no proof that extragalactic rays existed. If the cosmic rays’ origin could be found, scientists could isolate particles inside the rays to study their properties.

Unfortunately, it is difficult to locate the source of cosmic rays because they are anisotropic. Their properties changed when they encountered our galaxy’s magnetic field, which made determining the cosmic rays’ extragalactic properties impossible.

In the movie The Martian, the stranded Mark Watney wears a fashionable suit. Photo credits: Aidan Monaghan

So what does all of this mean? If we could source and isolate extragalactic cosmic rays, we could study how radiation damage affects the brain. We could create astronaut suits from materials that would deflect cosmic radiation, so astronauts can spend time on Mars without compromising their health. The groundbreaking discovery of extragalactic cosmic rays takes us one step closer to understanding the universe.

Jessica Shi