Solar powered cells are an area of rapid research, as solar energy is abundant, clean, sustainable, and available in most areas of the world. These solar powered cells are also known as solar photovoltaic (PV) cells because photons from sunlight are converted into electricity (Philibert 2011). The material that makes up the PV cell has a property that allows the material to absorb light photons and release electrons (Knier 2002). The free electrons are captured and flow through a circuit generating an electric current. Ideally, the material is efficient, inexpensive, durable, and easily manufactured. Despite some problems, an inorganic crystalline substance known as perovskite provides several advantages over other materials used in PV cells (Philibert 2011).
The following video describes how PV cells work. Video credit: YouTube user bcheng42 via YouTube.
Researchers have worked hard to increase the efficiency of PV cells so that solar energy is converted to electricity, and become a viable alternate to fossil fuels. Silicon-based cells are the most widely utilized material, as their efficiency of 20% outperforms all other types of cells (NTU New Release). However, experts note that the efficiency of silicon cells improved by less than 1% over the past decade. In contrast, the efficiency of perovskite increased quickly over the past five years. The efficiency of perovskite was 3.8% in 2009, 6.5% in 2011, and 15% in 2013. This large increase in efficiency indicates that perovskite may hold a promising future as a material in PV cells.
In addition, perovskite easily precipitates from a low cost solution stored at 80ºC. In contrast, silicon PV cells are manufactured at extremely high temperatures that require expensive manufacturing facilities (University of Nebraska-Lincoln). In fact, it is about five times cheaper to synthesize perovskite than silicon (NTU news release).
Thirdly, perovskite is advantageous since it precipitates out of solution in an almost perfect crystalline structure. The nearly perfect symmetry allows free electrons to travel through the material to the electrodes to produce an electric current (Science Magazine). If the material has a defective crystalline structure, the electron is impeded resulting in lower power production.

Perovskite has an almost perfect crystalline structure, making it an excellent material for PV cells. Photo credit: R.H. Buttner & E.N. Maslen via Wikimedia Commons.
Fourthly, it may be possible to layer perovskite on top of silicon, providing researchers with exciting possibilities for PV cells. Perovskite is better at capturing photons in the blue and green spectrum, whereas silicon is better at capturing photons in the red and infrared areas. By combining these two materials, it may be possible to reach efficiencies of 30%.
Currently, scientists are trying to overcome some drawbacks with perovskite. Research is needed to stop the breakdown of perovskite in the presence of oxygen or water. Furthermore, perovskite production is currently limited to the size of a postage stamp. The larger silicion cells are metres in length and capture more sunlight. Finally, perovskite contains lead, an undesirable environmental toxin. Despite these challenges, researchers are enthusiastically working to conquer these obstacles. In fact, perovskite is considered to be one of the breakthrough discoveries of 2013.
By: Jason Leung














