Category Archives: Uncategorized

An asymmetric reductase for acyclic imino acids

Acyclic imines are unstable in aqueous conditions, but acyclic imino acids can exhibit transient aqueous stability. Here we report the X-ray crystal structure and mechanism of Bsp5, an asymmetric acyclic imino acid reductase that intercepts acyclic imino acids produced by a partner oxidase and then converts them into D-amino acids. To read more, check out our recent paper in JACS!

Congratulations to Jin, Mel, and Phil on this work!

Farewell to Jin

It was Jin’s last day, and we sent her off with a goodbye lunch. She is off to join Applied Biological Materials (ABM) in Richmond, BC where she will be doing some cool work in biotech.

Good luck, Jin! We will miss you!

 

A Two-Enzyme Pathway Links L-Arg to Nitric Oxide in N-Nitroso Biosynthesis

N-nitroso compounds are carcinogenic molecules previously thought to be made only through non-enzymatic routes. We investigated how the N-nitroso natural product streptozocin is constructed, and we revealed a new two-enzyme pathway that links L-arginine to production of nitric oxide. Congratulations to Hai-Yan and coauthors for their recent publication in JACS!